Rafael Prado Gotor

Profesor Titular de Universidad
pradogotor@us.es
Área de conocimiento: Química Física
Departamento: Química Física
Grupo: Síntesis y Fisicoquímica de Nanopartículas (FQM-386)
Prog. doctorado: Programa de Doctorado en Química (RD. 99/2011)
Tipo Año Título Fuente
Artículo2021 Biocompatible DNA/5-fluorouracil-gemini surfactant-functionalized gold nanoparticles as promising vectors in lung cancer therapy PHARMACEUTICS
Artículo2021 Colorimetric, naked-eye detection of lysozyme in human urine with gold nanoparticles NANOMATERIALS
Artículo2021 Encased gold nanoparticle synthesis as a probe for oleuropein self-assembled structure formation MATERIALS
Artículo2021 Lysozyme–aunps interactions: determination of binding free energy NANOMATERIALS
Corrección2020 Author Correction: Design of highly stabilized nanocomposite inks based on biodegradable polymer-matrix and gold nanoparticles for Inkjet Printing (Scientific Reports, (2019), 9, 1, (16097), 10.1038/s41598-019-52314-2) SCIENTIFIC REPORTS
Artículo2020 Citrate and polyvinylpyrrolidone stabilized silver nanoparticles as selective colorimetric sensor for aluminum (III) ions in realwater samples MATERIALS
Artículo2020 Factors that control the gold nanoparticles' aggregation induced by adenine molecules: New insights through a combined experimental and theoretical study JOURNAL OF MOLECULAR LIQUIDS
Artículo2020 Reversible cationic gemini surfactant-induced aggregation of anionic gold nanoparticles for sensing biomolecules COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
Artículo2020 Theoretical study on the interactions between ibrutinib and gold nanoparticles for being used as drug delivery in the chronic lymphocytic leukemia JOURNAL OF MOLECULAR LIQUIDS
Artículo2020 Understanding gold nanoparticles interactions with chitosan: Crosslinking agents as novel strategy for direct covalent immobilization of biomolecules on metallic surfaces JOURNAL OF MOLECULAR LIQUIDS
Artículo2019 Chitosan as a capping agent: Insights on the stabilization of gold nanoparticles CARBOHYDRATE POLYMERS
Artículo2019 Design of highly stabilized nanocomposite inks based on biodegradable polymer-matrix and gold nanoparticles for Inkjet Printing SCIENTIFIC REPORTS
Artículo2019 What controls the unusual melting profiles of small AuNPs/DNA complexes PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Artículo2018 Decorating a single giant DNA with gold nanoparticles RSC ADVANCES
Artículo2018 Ethanol effect on gold nanoparticle aggregation state and its implication in the interaction mechanism with DNA JOURNAL OF COLLOID AND INTERFACE SCIENCE
Revisión2018 Exploring Factors for the Design of Nanoparticles as Drug Delivery Vectors CHEMPHYSCHEM
Artículo2017 A colorimetric study of the interaction of cationic and anionic surfactants with anionic gold nanoparticles COLLOID AND POLYMER SCIENCE
Revisión2017 Covalent and Non-Covalent DNA-Gold-Nanoparticle Interactions: New Avenues of Research CHEMPHYSCHEM
Artículo2017 Quantification of nucleobases/gold nanoparticles interactions: energetics of the interactions through apparent binding constants determination PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Artículo2017 Understanding and improving aggregated gold nanoparticle/dsDNA interactions by molecular spectroscopy and deconvolution methods PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Artículo2017 Understanding AuNP interaction with low-generation PAMAM dendrimers: a CIELab and deconvolution study JOURNAL OF NANOPARTICLE RESEARCH
Artículo2016 Native and modified chitosan-based hydrogels as green heterogeneous organocatalysts for imine-mediated Knoevenagel condensation APPLIED CATALYSIS A-GENERAL
Artículo2015 CIELab chromaticity evolution to measure the binding free energy of non-colored biomolecules to gold nanoparticles RSC ADVANCES
Artículo2015 Direct effect of tetrahedral alcohol species on the SPB of gold colloids: a deconvolution study JOURNAL OF NANOPARTICLE RESEARCH
Artículo2015 DNA conformational changes induced by cationic gemini surfactants: the key to switching DNA compact structures into elongated forms RSC ADVANCES
Artículo2015 Fluorescent imino and secondary amino chitosans as potential sensing biomaterials CARBOHYDRATE POLYMERS
Artículo2015 Interaction of gold nanoparticles mediated by captopril and S-nitrosocaptopril: the effect of manganese ions in mild acid medium PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Revisión2015 Nonfunctionalized Gold Nanoparticles: Synthetic Routes and Synthesis Condition Dependence CHEMISTRY-A EUROPEAN JOURNAL
Artículo2015 Synthesis of hyperpolarizable biomaterials at molecular level based on pyridinium-chitosan complexes RSC ADVANCES
Capítulo2014 Aplicación de un modelo didáctico alternativo a la asignatura de fisicoquímica I Seminario Iberoamericano de Innovación Docente de la Universidad Pablo de Olavide.
Ponencia2014 Aprendizaje significativo del alumnado de física aplicada del grado en farmacia: evaluación basada en el empleo de cuestionarios. ARS PHARMACEUTICA
Artículo2014 DNA Strand Elongation Induced by Small Gold Nanoparticles at High Ethanol Content JOURNAL OF PHYSICAL CHEMISTRY C
Artículo2014 Electronically tunable anion-pi interactions in pyrylium complexes: experimental and theoretical studies PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Artículo2014 Free energy of binding of cationic metal complexes to AuNPs through electron-transfer processes SOFT MATTER
Ponencia2014 Interdisciplinariedad de la nueva asignatura de Física Aplicada a las Ciencias de la Salud: evaluación de competencias complementarias en el ámbito de Farmacia y Ciencias de la Salud FECIES 2013: X Foro Internacional sobre Evaluación de la Calidad de la Investigación y de la Educación Superior
Artículo2014 Noncovalent Interactions of Tiopronin-Protected Gold Nanoparticles with DNA: Two Methods to Quantify Free Energy of Binding SCIENTIFIC WORLD JOURNAL
Artículo2014 Use of gold nanoparticles as crosslink agent to form chitosan nanocapsules: Study of the direct interaction in aqueous solutions JOURNAL OF INORGANIC BIOCHEMISTRY
Artículo2013 AuNPs-DNA non-covalent interactions: improve of some studies and new avenues of research from negative results The All Results Journal: Chem
Artículo2013 Binding Study of the [Ru(NH3)(5)pz](2+) Complex to Bile Anion Aggregates through Kinetic Measurements INTERNATIONAL JOURNAL OF CHEMICAL KINETICS
Artículo2013 Improving the understanding of DNA-propanediyl-1,3-bis(dodecyldimethylammonium) dibromide interaction using thermodynamic, structural and kinetic approaches PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Capítulo2012 DNA surface recognition: Non-covalent DNA-aunps interactions DNA Binding and DNA Extraction: Methods, Applications and Limitations
Artículo2012 Electrochemiluminescence of the [Ru(bpy)(3)](2+) Complex: The Coreactant Effect of PAMAM Dendrimers in an Aqueous Medium INORGANIC CHEMISTRY
Artículo2012 The Fluorophore 4 ',6-Diamidino-2-phenylindole (DAPI) Induces DNA Folding in Long Double-Stranded DNA CHEMISTRY-AN ASIAN JOURNAL
Artículo2012 Thermodynamic and structural study of phenanthroline derivative ruthenium complex/DNA interactions: Probing partial intercalation and binding properties JOURNAL OF INORGANIC BIOCHEMISTRY
Artículo2011 A kinetic study of the interaction of DNA with gold nanoparticles: mechanistic aspects of the interaction PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Artículo2010 Solvent Effects on the Kinetics of the Interaction of 1-Pyrenecarboxaldehyde with Calf Thymus DNA JOURNAL OF PHYSICAL CHEMISTRY B
Artículo2010 Thermodynamic and structural study of pyrene-1-carboxaldehyde/DNA interactions by molecular spectroscopy: Probing intercalation and binding properties CHEMICAL PHYSICS
Artículo2008 Quantification of salts and cosolvents-DNA interactions in terms of free energies: A study using the pyren-1-carboxyaldehyde as fluorescent probe CHEMICAL PHYSICS
Artículo2008 Restricted geometry conditions promoted by AlOOH nanoparticles: Variable strength and character of AlOOH-cluster/charged ligand interactions as a consequence of changes in the solvent JOURNAL OF PHYSICAL CHEMISTRY C
Artículo2008 Two-state model based on electron-transfer reactivity changes to quantify the noncovalent interaction between Co(NH3)(5) Cl2+ and 18-crown-6 ether: The effect of second-sphere coordination on electron-transfer processes JOURNAL OF PHYSICAL CHEMISTRY A
Artículo2007 Kinetic approach for the study of noncovalent interaction between [Ru(NH3)(5)pz](2+) and gold nanoparticles JOURNAL OF PHYSICAL CHEMISTRY A
Artículo2007 Non-covalent interactions between Co(en)(2)Cl-2(+) and SDS micelles: A comparison between experimentally and EMSA-calculated free energies of binding CHEMICAL PHYSICS LETTERS
Libro2007 Recent studies in solution chemistry: fundamentals and applications Recent studies in solution chemistry: fundamentals and applications
Artículo2006 A study of the non-electrostatic interaction micelle/charged ligand: A comparison of the results obtained by two different methods CHEMICAL PHYSICS LETTERS
Artículo2006 Cylodextrins effects in the substitution reaction of 4,4 '-bpy for the aquo ligand in aquopentacyanoferrate(II): an estimation of the binding constants of the reactant and the transition state to cyclodextrins CHEMICAL PHYSICS
Artículo2006 Electrolyte effects on the intervalence transition within discrete binuclear cyano-bridged complexes. An estimation of activation free energy from static, optical and electrochemical data INORGANICA CHIMICA ACTA
Artículo2006 Salt and solvent effects on the kinetics and thermodynamics of the inclusion of the ruthenium complex [Ru(NH3)(5)(4,4 '-bpy)](2+) in beta-cyclodextrin JOURNAL OF PHYSICAL CHEMISTRY B
Artículo2006 Salt and solvent effects on the kinetics of the oxidation of the excited state of the [Ru(bPY)(3)](2+) complex by S2O82- JOURNAL OF PHYSICAL CHEMISTRY A
Artículo2005 "Abnormal" salt and solvent effects on anion/cation electron-transfer reactions: An interpretation based on Marcus-Hush treatment JOURNAL OF PHYSICAL CHEMISTRY B
Artículo2005 Asymmetric salt effects on anion/cation reactions: A comparative study of the [Fe(CN)(6)]4(-) +[Co(NH3)(5)pz](3+) and [Ru(NH3)(5)pz](2+) + [Co(C2O4)(3)](3-) reactions INTERNATIONAL JOURNAL OF CHEMICAL KINETICS
Artículo2005 DNA effects upon the reaction between acetonitrile pentacyanoferrate(II) and ruthenium pentammine pyrazine: Kinetic and thermodynamic evidence of the interaction of DNA with anionic species CHEMICAL PHYSICS
Artículo2005 Method for the evaluation of the reorganization energy of electron transfer reactions in water-methanol mixtures CHEMICAL PHYSICS LETTERS
Artículo2005 Method for the evaluation of the reorganization energy of electron transfer reactions produced under restricted geometry conditions JOURNAL OF PHYSICAL CHEMISTRY B
Artículo2005 Strength and character of peptide/anion interactions JOURNAL OF PHYSICAL CHEMISTRY B
Artículo2004 DNA interactions with small solutes: change in the character of the binding of [Ru(NH3)(5)pz](2+) to DNA as a consequence of changes in the solvent CHEMICAL PHYSICS
Artículo2004 Effects of SB1.5G and SB4.5G dendrimers on the rate of the electron transfer reaction between [Ru(NH3)(5)pz](2+) and [CO(C2O4)(3-) CHEMICAL PHYSICS LETTERS
Artículo2004 Micellar effects on a ligand substitution reaction: Kinetics of the formation of [Fe(CN)(5)(mu-pz)Ru(NH3)(5)](-), from [Fe(CN)(5)H2O](3-) and [Ru(NH3)(5)pz](2+), in the presence of anionic micelles INTERNATIONAL JOURNAL OF CHEMICAL KINETICS
Artículo2004 On the equivalence of the pseudophase related models and the bronsted approach in the interpretation of reactivity under restricted geometry conditions PROGRESS IN REACTION KINETICS AND MECHANISM
Artículo2004 Polymerization-induced enhancement of binding and binding-induced polymerization CHEMICAL PHYSICS LETTERS
Artículo2004 Solvent effects on the oxidation (electron transfer) reaction of [Fe(CN)(6)](4-) by [Co(NH3)(5)pz](3+) CHEMICAL PHYSICS
Artículo2004 Studies on medicinal plants of Ivory Coast: Investigation of Sida acuta for in vitro antiplasmodial activities and identification of an active constituent PHYTOMEDICINE
Artículo2004 Study of the base-catalyzed nitrito-nitro isomerization reaction ([(NH3)(5)Co-ONO](2+)->[(NH3)(5)Co-NO2](2+)) in mixed solvents INTERNATIONAL JOURNAL OF CHEMICAL KINETICS
Artículo2004 Synthesis, structure, magnetic and electrochemical properties of an oxydiacetate iron(II) complex INORGANICA CHIMICA ACTA
Ponencia2003 A rationally designed CD4 mimic useful in HIV inhibition and vaccine design BIOPOLYMERS
Artículo2003 Comparative study of micellar and DNA effects on the reaction [Ru(NH3)(5py)](2+)+S2O82- LANGMUIR
Artículo2003 Influence of the charge and concentration of coreactants on the apparent binding constant of the reactant to micelles LANGMUIR
Artículo2003 Rational design of a CD4 mimic that inhibits HIV-1 entry and exposes cryptic neutralization epitopes Nature Biotechnology
Artículo2003 Solvent and salt effects on the kinetics of the reaction between [Ru(NH3)(5)pz](2+) and [Fe(CN)(5)H2O](3-) INTERNATIONAL JOURNAL OF CHEMICAL KINETICS
Artículo2002 In vitro antiplasmodial activity of extracts of Alchornea cordifolia and identification of an active constituent: ellagic acid JOURNAL OF ETHNOPHARMACOLOGY
Artículo2002 Salt effects on reactivity for the formation and dissociation of bis-(ethane-1,2-diamine)cobalt(III)-mu-pyrazinecarboxylato-pentacyanoferrate(II) TRANSITION METAL CHEMISTRY
Artículo2001 Effect of DNA on the rate of electron transfer reactions between non-intercalated reactants: kinetic study of the reactions [Ru(NH3)(5)pz](2+)+[Co(C2O4)(3)](3-) and [Ru(NH3)(5)py](2+)+[Co(NH3)(4)pzCO(2)](2+) in aqueous solutions in the presence of DNA PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Artículo2001 Electron transfer reactions in micellar systems: Separation of the true (unimolecular) electron transfer rate constant in its components CHEMICAL PHYSICS
Revisión2000 Electron transfer reactions in micellar systems PROGRESS IN REACTION KINETICS AND MECHANISM
Revisión2000 Electron transfer reactions in solvent mixtures: the excess component of solvent reorganization free energy COORDINATION CHEMISTRY REVIEWS
Artículo2000 Influence of the micellar electric field on electron-transfer processes (II): A study of the Ru(NH3)(5)pz(2+)+Co(C2O4)(3)(3-) reaction in SDS micellar solution containing NaCl LANGMUIR
Artículo1998 A study of the electron-transfer reaction between Fe(CN)(2)(bpy)(2) and S2O82- in solvent mixtures: the translational component of solvent reorganization NEW JOURNAL OF CHEMISTRY
Artículo1998 Micellar effects upon the reaction between acetonitrile pentacyanoferrate(II) and bis(ethylenediammine)(2-pyrazinecarboxylato)cobalt(III) LANGMUIR
Artículo1997 Kinetic study of the Fe(bpy)(3)(2+)+S2O82- reaction in solvent mixtures BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Proyectos de Investigación

Fecha de inicio Fecha de fin Rol Denominación Agencia financiadora
01/11/1996 01/11/1999 Investigador/a EFECTOS DE CAMPOS ELECTRICOS Y DINAMICOS DEL DISOLVENTE EN REACCIONES DE TRANSFERENCIA ELECTRONICA (PB950535)
01/03/2006 28/02/2009 Investigador/a Estudio de las interacciones no covalentes del ADN con distintos ligandos: aplicaciones a la construcción de sensores de ADN y sistemas de transporte genético (EXC/2005/FQM-162) Junta de Andalucía (Plan Andaluz de Investigación) (Autonómico)
30/12/2016 29/12/2019 Investigador/a Moléculas y Macromoléculas con Actividad Multidiana frente a enfermedades Degenerativas (CTQ2016-78703-P) Ministerio de Economía y Competitividad (Nacional)
01/01/1999 31/12/2000 Investigador/a EFECTOS DE CAMPOS ELECTRICOS Y DINAMICOS DEL DISOLVENTE EN REACCIONES DE TRANSFERENCIA ELECTRONICA CON PARTICIPACION DE ESPECIES ELECTRONICAMENTE EXCITADAS
31/12/2005 31/12/2008 Investigador/a Estudio de las interacciones no covalentes tipo receptor/sustrato y de sus efectos sobre la reactividad química de los sustratos (CTQ2005-01392) Ministerio de Educación y Ciencia (Nacional)
01/11/2002 31/10/2005 Investigador/a Estudios sobre reactividad química en condiciones de geometría restringida (BQU2002-01063) Ministerio de Ciencia y Tecnología (Nacional)
13/01/2009 31/12/2013 Investigador/a Interacciones ADN/Ligandos: Estudios Cinético y Termodinámico. Aplicación al Desarrollo de Vectores para Transporte Genético, al Desarrollo de Sensores y a las Aplicaciones del ADN como Catalizador. (P08-FQM-03623) Junta de Andalucía - Consejería de Innovación, Ciencia y Empresas (Autonómico)
01/01/2009 31/12/2012 Investigador/a Estudio termodinámico y cinético de la formación de complejos ligando/receptor y de la influencia de la formación de complejos en la reactividad química de los ligandos (CTQ2008-00008) Ministerio de Ciencia e Innovación (Nacional)

Contratos

Fecha de inicio Fecha de fin Rol Denominación Agencia financiadora
01/02/2018 31/03/2018 Responsable "Determinación del punto de ebullición y tensión de vapor de esencias: VAPOUR TENSION" (3285/0928) Sensient Fragances S.A.U. (Autonómico)

Ayudas

Fecha de inicio Fecha de fin Rol Denominación Agencia financiadora
07/04/2005 07/04/2007 Investigador/a XVIITH Spanish-Italian congress on the thermodynamics of metal complexes (CTQ2004-22001-E) Ministerio de Educación y Ciencia (Nacional)
11/11/2010 15/03/2011 Responsable Desarrollo de un kit de detección de ADN de doble hebra y de tensioactivos aniónicos basados en nanoparticulas de oro (OTR2010-CT20) Universidad de Sevilla (Oficina de Transferencia de Resultados de Investigación) (Local)