Francisco J. Montilla Ramos

Catedrático de Universidad
montilla@us.es
Área de conocimiento: Química Inorgánica
Departamento: Química Inorgánica
Grupo: ORGANOMETALICOS Y CATALISIS HOMOGENEA (FQM-223)
Prog. doctorado: Programa de Doctorado en Química (RD. 99/2011)
Tipo Año Título Fuente
Capítulo2021 Chapter 10: use of vanadium catalysts in epoxidation and sulphoxidation reactions with green chemistry criteria RSC Catalysis Series
Revisión2021 P atom as ligand in transition metal chemistry: structural aspects COORDINATION CHEMISTRY REVIEWS
Artículo2020 Homochiral imidazolium-based dicarboxylate compounds: Structure and solution behaviour INORGANICA CHIMICA ACTA
Artículo2019 Synthesis and structural characterization of homochiral coordination polymers with imidazole-based monocarboxylate ligands DALTON TRANSACTIONS
Artículo2018 Molybdenum-Catalyzed Enantioselective Sulfoxidation Controlled by a Nonclassical Hydrogen Bond between Coordinated Chiral Imidazolium-Based Dicarboxylate and Peroxido Ligands MOLECULES
Artículo2018 Oxidoperoxidomolybdenum(VI) complexes with acylpyrazolonate ligands: synthesis, structure and catalytic properties DALTON TRANSACTIONS
Artículo2018 Synthesis of ,-Dicarbonylhydrazones by Aerobic Manganese-Catalysed Oxidation ADVANCED SYNTHESIS & CATALYSIS
Capítulo2017 Spectroscopic and Structural Characterization of Carbon Dioxide Transition Metal Complexes ADVANCES IN ORGANOMETALLIC CHEMISTRY, VOL 68
Artículo2017 Synthesis and structural characterization of homochiral 2D coordination polymers of zinc and copper with conformationally flexible ditopic imidazolium-based dicarboxylate ligands DALTON TRANSACTIONS
Artículo2016 Influence of the ionic liquid presence on the selective oxidation of glucose over molybdenum based catalysts CATALYSIS TODAY
Artículo2016 Molybdenum-catalyzed asymmetric sulfoxidation with hydrogen peroxide and subsequent kinetic resolution, using an imidazolium-based dicarboxylate compound as chiral inductor CATALYSIS COMMUNICATIONS
Artículo2015 Ionic liquid immobilization on carbon nanofibers and zeolites: Catalyst design for the liquid-phase toluene chlorination COMPTES RENDUS CHIMIE
Artículo2015 Oxido- versus imido-transfer reactions in oxido-imido molybdenum(VI) complexes: A combined experimental and theoretical study POLYHEDRON
Artículo2015 Oxodiperoxomolybdenum complex immobilized onto ionic liquid modified SBA-15 as an effective catalysis for sulfide oxidation to sulfoxides using hydrogen peroxide CATALYSIS TODAY
Artículo2015 Synthesis, characterization and structure of nickel and copper compounds containing ligands derived from keto-enehydrazines and their catalytic application for aerobic oxidation of alcohols DALTON TRANSACTIONS
Artículo2014 Experimental and theoretical insights into the oxodiperoxomolybdenum-catalysed sulphide oxidation using hydrogen peroxide in ionic liquids DALTON TRANSACTIONS
Artículo2013 Dioxomolybdenum(VI) Complexes with Acylpyrazolonate Ligands: Synthesis, Structures, and Catalytic Properties EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Artículo2013 Interaction between monomers of two surfactants derived from the [Ru(2,2 '-bpy)(3)](2+) complex and alpha, beta and gamma-cyclodextrins: formation of [2]- and [3]-pseudorotaxanes DALTON TRANSACTIONS
Artículo2013 Molybdenum-catalysed oxidation of cyclohexene with hydrogen peroxide in the presence of alcohols and X-ray structures of octamolybdate [C(4)mim](4)[Mo8O26] and tetraperoxodimolybdate [Htmpy](2)[{MoO(O-2)(2)}(2)(mu-O)] complexes POLYHEDRON
Artículo2012 New insights into the mechanism of oxodiperoxomolybdenum catalysed olefin epoxidation and the crystal structures of several oxo-peroxo molybdenum complexes DALTON TRANSACTIONS
Artículo2012 On the applicability of the two state (pseudophase) model to photochemical reactions under restricted geometry conditions JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Artículo2011 Deactivation of the Cobalt Catalyst for the Cyclotrimerization of Acetylenes in Ionic Liquids: Solvent Effects on the Mechanism and Thermal and Pressure Activation Parameters ORGANOMETALLICS
Artículo2011 Influence of N-donor bases and the solvent in oxodiperoxomolybdenum catalysed olefin epoxidation with hydrogen peroxide in ionic liquids DALTON TRANSACTIONS
Artículo2011 Olefin epoxidation in solventless conditions and apolar media catalysed by specialised oxodiperoxomolybdenum complexes JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Artículo2010 Olefin epoxidation by hydrogen peroxide catalysed by molybdenum complexes in ionic liquids and structural characterisation of the proposed intermediate dioxoperoxomolybdenum species CHEMICAL COMMUNICATIONS
Artículo2010 Supercritical carbon dioxide, a new medium for aerobic alcohol oxidations catalysed by copper-TEMPO DALTON TRANSACTIONS
Artículo2010 Synthesis and theoretical analysis of palladium complexes of polydimethylsiloxane functionalised pyridine and their catalytic activity in alcohol oxidations under low polar conditions POLYHEDRON
Artículo2009 Methyltrioxorhenium Complexes of Polydimethylsiloxane-Functionalized Pyridine as Efficient Olefin Epoxidation Catalysts in Solventless and Low-Polar Solvent Conditions ORGANOMETALLICS
Artículo2009 Oil shale phenol-derived aerogels as supports for palladium nanoparticles OIL SHALE
Artículo2009 Olefin epoxidations in the ionic liquid [C(4)mim][PF6] catalysed by oxodiperoxomolybdenum species in situ generated from molybdenum trioxide and urea-hydrogen peroxide: The synthesis and molecular structure of [Mo(O)(O-2)(2)(4-MepyO)(2)]center dot H2O POLYHEDRON
Artículo2008 Preparation of the catalyst support from the oil-shale processing by-product The Open Petroleum Engineering Journal
Artículo2007 Catalytic epoxidation of cyclooctene using molybdenum(VI) compounds and urea-hydrogen peroxide in the ionic liquid [bmim]PF6 CATALYSIS COMMUNICATIONS
Artículo2007 The use of pyridine-functionalised polydimethylsiloxane polymers as a supercritical carbon dioxide solubilising support for copper compounds INORGANIC CHEMISTRY COMMUNICATIONS
Artículo2006 Carbosilane dendrons as solubilizers of metal complexes in Supercritical carbon dioxide ORGANOMETALLICS
Artículo2006 Use of vanadium complexes as catalysts in the synthesis of guanidines: New experimental data and DFT analysis of the carbodiimide interaction with the catalyst ORGANOMETALLICS
Ponencia2005 Solid-state Formation of a Coordination Polymer Starting from a Monomeric Thiodiacetate Manganese Complex ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES
Ponencia2005 Structural Features of Oxydiacetate and Thiodiacetate Complexes and Crystal Structures of Magnesium Derivatives ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES
Artículo2004 Effect of trimethylsilyl substitution on the chemical properties of triarylphosphines and their corresponding metal-complexes: Solubilising effect in supercritical carbon dioxide DALTON TRANSACTIONS
Artículo2004 Guanylation of aromatic amines catalyzed by vanadium imido complexes JOURNAL OF ORGANOMETALLIC CHEMISTRY
Artículo2004 Manganese oxydiacetate complexes: Synthesis, structure and magnetic properties EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Artículo2004 Phase behaviour of the catalyst dicarbonyl (eta(5)-cyclopentadienyl)-cobalt in carbon dioxide The Journal of Supercritical Fluids
Artículo2003 Trimethylsilyl-substituted ligands as solubilizers of metal complexes in supercritical carbon dioxide DALTON TRANSACTIONS
Artículo2002 Hydroformylation of alkenes in supercritical carbon dioxide catalysed by rhodium trialkylphosphine complexes JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Artículo2002 Synthesis and molecular structure of the nitride (L-OEt)Mo(N)Cl-2 [L-OEt = (eta-C5H5)CO{P(O)(OEt)(2)}3] JOURNAL OF ORGANOMETALLIC CHEMISTRY
Artículo2001 CPCO(CO)(2)-catalysed cyclotrimerisation of alkynes in supercritical carbon dioxide JOURNAL OF ORGANOMETALLIC CHEMISTRY
Artículo2001 Transition-metal-mediated activation of arylisocyanates in supercritical carbon dioxide JOURNAL OF ORGANOMETALLIC CHEMISTRY
Artículo2000 MO rationalization of the synthesis and structure of V(N-2,6-(Pr2C6H3)-Pr-i)Cl(CO)(2)(PMe3)(2) complex ORGANOMETALLICS
Artículo2000 Steric versus electronic effects in six-co-ordinate d(o) cis-bis(imido) molybdenum complexes JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Artículo1999 Synthesis and characterization of d(0) imido complexes of vanadium. Crystal structure of [V(2,6-(Pr2C6H3N)-Pr-i)(S2CNC4H4)(3)] JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Artículo1999 Synthesis and characterization of d(2)-molybdenum imido complexes containing coordinated dithio-ligands. MO rationalization of the preferential isomer formation of Mo(N-2,4,6-Me3C6H2)(S2COMe)Cl(PMe3)(2) JOURNAL OF ORGANOMETALLIC CHEMISTRY
Artículo1999 Synthesis and characterization of dioxocomplexes of molybdenum with (eta-C5H5)Co{P(O)(OEt)(2)}(3), C5H4(SiMe3) and 1,3-C5H3(SiMe3)(2) ligands. X-ray crystal structure of [(eta-C5H5)Co{P(O)(OEt)(2)}(3)]MoO2Cl POLYHEDRON
Artículo1999 Synthesis and characterization of oxo-imido and alkyl-imido complexes of molybdenum(VI) JOURNAL OF ORGANOMETALLIC CHEMISTRY
Artículo1999 Synthesis, structural characterization, and MO calculations of vanadium imido complexes containing bidentate phosphine coligands INORGANIC CHEMISTRY
Artículo1998 Synthesis and characterization of d(2) imido complexes of molybdenum. Crystal structure of [MoCl2{N(mes)}(PhC CPh)-(PMe3)(2)]center dot O.5PhC equivalent to CPh (mes = 2,4,6-trimethylphenyl) JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Artículo1997 Synthesis and characterization of (2,4,6-trimethylphenylimido)molybdenum complexes. X-ray crystal structures of (L-OEt)Mo(Nmes)(2)Cl, (L-OEt)Mo(Nmes)Cl-2, and MoCl3(Nmes)(depe) (mes equals 2,4,6-trimethylphenyl, L-OEt=(eta-C5H5)Co{P(O)(OEt)(2)}(3), depe equals Et2PCH2CH2PEt2) INORGANIC CHEMISTRY
Ponencia1997 Synthesis and characterization of new imido complexes of molybdenum. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY

Proyectos de Investigación

Fecha de inicio Fecha de fin Rol Denominación Agencia financiadora
01/01/2011 31/12/2014 Investigador/a Nuevos Sistemas Catalíticos en Química Sostenible Mediante el Empleo de Disolventes Alternativos (CTQ2010-15515) Ministerio de Ciencia e Innovación (Nacional)
01/06/2004 31/05/2008 Responsable Green Chemistry in Supercritical Fluids: Phase Behaviour, Kinetics and Scale-up (SUPERGREENCHEM) (MRTN-CT-2004-504005) Commission of the European Communities (Research Directorate-General) (Europeo)
31/01/2008 31/12/2012 Investigador/a Hacia una Química Sostenible: Utilización de Disolventes no Convencionales en los Nuevos Procesos Catalíticos de Síntesis (P07-FQM-02474) Junta de Andalucía - Consejería de Innovación, Ciencia y Empresas (Autonómico)
13/12/2004 12/06/2007 Investigador/a Nuevos catalizadores metálicos para procesos de oxidación selectiva en dióxido de carbono supercrítico empleando O2 y H202 como oxidantes no contaminantes: diseño, síntesis y aplicaciones (CTQ2004-00084) Ministerio de Ciencia y Tecnología (Nacional)
01/10/2007 31/03/2011 Investigador/a Desarrollo de nuevos catalizadores homogéneos en líquidos iónicos y dióxido de carbono supercrítico (CTQ2007-61037) Ministerio de Educación y Ciencia (Nacional)
01/01/2019 31/12/2021 Investigador/a Catálisis Asimétrica en Medio Acuoso Mediada por Complejos Metálicos con Carbenos Quirales de Tipo N-Heterocíclico (Nhcs) (PGC2018-093443-B-I00) Ministerio de Ciencia, Innovación y Universidades (Nacional)
28/12/2001 28/12/2004 Investigador/a Síntesis, caracterización y estudio de las propiedades y aplicaciones de compuestos de vanadio y molibdeno estabilizados por ligandos donadores (BQU2001-3715) Ministerio de Ciencia y Tecnología (Nacional)
01/03/2006 28/02/2009 Investigador/a Compuestos de los elementos de los grupos 9, 10 y 12 que contienen enlaces M-C. Aspectos fundamentales y aplicaciones prácticas (EXC/2005/FQM-672) Junta de Andalucía (Plan Andaluz de Investigación) (Autonómico)
26/03/2013 31/05/2018 Investigador/a Química Verde: Catálisis en Líquidos Iónicos y en Ausencia de Disolvente (P11-FQM-7079) Junta de Andalucía - Consejería de Innovación, Ciencia y Empresas (Autonómico)
01/10/1998 01/10/2001 Investigador/a COMPUESTOS DE VANADIO Y MOLIBDENO QUE CONTIENEN LIGANDOS IMIDURO, OXO Y NITROSILO: SINTESIS, ESTRUCTURA Y REACTIVIDAD (PB97-0740)

Contratos

Fecha de inicio Fecha de fin Rol Denominación Agencia financiadora
12/07/2012 11/09/2012 Investigador/a Síntesis a escala del multigramo del quelante 0,0 - EDDHA (1601/0588) Establecimientos HEFE, S.L. (Local)

Ayudas

Fecha de inicio Fecha de fin Rol Denominación Agencia financiadora
01/01/2007 31/12/2008 Investigador/a Coordination metal organic polymers with heterocyclic N-donor and carboxylate ligands: polyfunctional porous materials (HI2006-0125) Ministerio de Educación y Ciencia (Nacional)